What is
Cannizzaro reaction?
Aldehydes that do not have an
alpha hydrogen atom undergo auto-oxidation reduction reactions when heated with
concentrated or 50% NaOH or KOH solutions.
That is, half of the
participating aldehydes molecules are oxidized to carboxylic acids (as sodium
or potassium salt)...
Tuesday, November 29, 2022
Friday, November 18, 2022
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202
Which is more covalent, AgCl,
NaCl, LiCl or KCl?
In
the above compounds, Cl– anion is common for all, but cations are
different. According
to Fajan’s rule, the covalent
character in ionic compounds depends on the size of cation, anion and charge of
both the cation and anion.
Now,
the cation with smaller...
Saturday, November 12, 2022
Why is Cu2+ ion more stable than Cu+ ion in aqueous solution?
Many Cu+ compounds
are not stable in aqueous solution. These
compounds undergo disproportionation reactions to form metallic copper and Cu2+
compounds.
&nb...
Monday, September 12, 2022
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202
Why is phenol more acidic than aliphatic alcohols?
Phenol
is acidic in nature. Because of phenol can donate proton in aqueous solution.
Although, phenol is weakly acidic but
phenol is more acidic than aliphatic alcohols.
The
strength of acid depends on the tendency of donating proton in aqueous...
Wednesday, June 1, 2022
Why do polar
solvent and weak nucleophiles favor SN1 reaction?
Polar
protic solvents, such as CH3OH, CH3CH2-OH, H2O, etc., are suitable for SN1
reactions. This is because in this type of solvent, both carbocation and halide
anion gain stability. That is, polar
protic solvent favor SN1 reaction mechanism...
Thursday, May 26, 2022
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Why do nucleophiles always attack from backside
in SN2 reactions?
The
SN2 reaction occurs in one step
through the backside attack. That is, in this reaction, the
nucleophile attacks the carbon atom of the substrate from the opposite side of
the living group.
The SN2 reaction is completed through...
Tuesday, May 17, 2022
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202
What is carbon disulfide?
Carbon
disulfide is also known as carbon bisulfide, is a neurotoxic colorless volatile
liquid with chemical formula, CS2. The IUPAC name of carbon
disulfide is methane dithione.
Carbon
disulfide is a colorless liquid in purest form and it is light yellow under
impure...
Tuesday, May 10, 2022
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What is carbon black?
Carbon
black material is also known as
acetylene black, channel black, furnace black, lamp black, and thermal black.
It is a black solid with molar mass 12.01 g/mol. The density of carbon black at 20°C is 1.8-2.1 g/cc.
...
Monday, May 2, 2022
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202
What is sodium hydrogen carbonate?
Sodium
hydrogen carbonate is also name as sodium bicarbonate, is a
chemical compound with molecular formula, NaHCO3. It is also known as an acidic
salt or bi salt, which is made from carbonic acid...
Thursday, March 17, 2022
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202
What
is catenation property of carbon?
Catenation property is found in organic as well as in
inorganic compounds. The catenation property mainly shows carbon element in
organic chemistry.
When
two or more atoms of an element combine with each other through the covalently
single bond,...
Monday, March 14, 2022
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202
What is chiral center or stereogenic center?
Optical
isomerism:
The isomerism in which two or more compounds have same
physical and chemical properties but they have different behavior towards plane
polarized light, are known as optical isomerism and such type of compounds are
known as optically active compounds.
Chiral
centers:
When...
Thursday, December 23, 2021
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202
What is ammonia water
in inorganic chemistry?
Ammonia water means aqueoussolution of ammonia. Ammonia water
is also known as ammonia liquor, aqueous ammonia, ammonium hydroxide, aqua
ammonia, ammoniacal liquor etc.
It
is symbolically expressed as NH3 (aq.)
or NH4OH. Ammonia water solution
has fishy and...